The Man from U.N.C.L.E. (1964)

Napoleon Solo (Robert Vaughn) and Illya Kuryakin (David McCallum), Agents for U.N.C.L.E. (the United Network Command for Law-Enforcement) are locked in a weekly derring-do battle with the nefarious schemes of T.H.R.U.S.H. (the Technological Hierarchy for the Removal of Undesirables and the Subjugation of Humanity).